Transition Metal Complexes of                                            4-aminobenzenesulfonamide 1,3-benzodioxole-5-carbaldehyde: Synthesis, Characterization and Biological Activities

J. Anandakumaran; M. L. Sundararajan; T. Jeyakumar; Mohammad Nasir Uddin

doi:10.9734/ACSJ/2016/22807

Research Article Open access CC BY 4.0

Transition Metal Complexes of 4-aminobenzenesulfonamide 1,3-benzodioxole-5-carbaldehyde: Synthesis, Characterization and Biological Activities

J. Anandakumaran, M. L. Sundararajan, T. Jeyakumar, Mohammad Nasir Uddin

Chemical Science International Journal · pp. 1–14 · Published 2 Dec 2015

10.9734/ACSJ/2016/22807

Abstract

Cu(II), Zn(II), Ni(II) and Cd(II) complexes with Schiff base ligand derived from piperonal and sulfanilamide have been synthesized and characterized by elemental (C, H and N) analysis, UV-Vis, IR, 1H and 13C NMR, mass spectra, thermal analysis (TG/DTA) and molar conductance measurements. The spectral data suggest that the coordination of metal ion with ligand is only through imine nitrogen (–CH=N–) as monodentate manner. Thermal analysis indicates the presence of lattice and coordinated water molecules in the complexes. Mass spectral data further support the formula mass and structure of the compounds. Biological activities of all the compounds were evaluated.

Sulfanilamide piperonal schiff base metal complexes

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J. Anandakumaran, M. L. Sundararajan, T. Jeyakumar, Mohammad Nasir Uddin (2015). Transition Metal Complexes of 4-aminobenzenesulfonamide 1,3-benzodioxole-5-carbaldehyde: Synthesis, Characterization and Biological Activities. Chemical Science International Journal , 1–14. https://doi.org/10.9734/ACSJ/2016/22807

Affiliations

J. Anandakumaran — Chemistry Section, Faculty of Engineering and Technology, Annamalai University, Annamalai Nagar 608 002, India
M. L. Sundararajan — Chemistry Section, Faculty of Engineering and Technology, Annamalai University, Annamalai Nagar 608 002, India
T. Jeyakumar — Chemistry Section, Faculty of Engineering and Technology, Annamalai University, Annamalai Nagar 608 002, India
Mohammad Nasir Uddin — Department of Chemistry, University of Chittagong, Chittagong - 4331, Bangladesh

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