1-Tosyl-2-trifluoroacetylindole as Promising Partner for Synthesis of Fused Fluorinated Heterocycles
Chemical Science International Journal · pp. 1–4 · Published 10 Apr 2019
10.9734/CSJI/2019/v26i430099Abstract
We prepared 1-tosyl-2-trifluoroacetylindole - a novel example of an electron-deficient indole with an electrophilic C(3) position. This substance was involved in cyclocondensation with a variety of amidines to propose a new general pathway to 8H-[4,5-b]indolopyrimidines with yield 50-80%. CF3-containing 5H-[3,2-d]indolopyrimidines were unknown before this study.
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