Synthesis and Characterization of Nano Structured Zinc(II) Cysteine Complex under Ultrasound Irradiation
Maryam Ranjbar, Nasrin Shahsavan, Mohammad Yousefi
Chemical Science International Journal · pp. 111–121 · Published 17 Oct 2012
10.9734/ACSJ/2012/1617Abstract
Cysteine and zinc oxides are important materials that have a wide range of applications especially in biomedical sciences. In this study, synthesis and characterization of nano structured Zn(II) complex of cysteine, (cysteine = 2-amino-3-mercaptopropanoic acid), in two different particle sizes, has been investigated. The reaction of Zinc(II) acetate and KI with cysteine ligand under ultrasonic irradiation, leads to the formation of nano sized Zn(II) cysteine complex. Particle sizes of the product have been decreased after thermal treatments in an autoclave. The hexagonal micro crystalline zinc oxide, has been prepared using Zn(II) cysteine complex as precursor. Characterization of the Zn(II) complex, has been performed using elemental analysis, FTIR spectroscopy, energy dispersed X-ray analysis (EDAX), scanning electron microscopy (SEM), thermal analysis (TG/DTA) and gel-permeation chromatography (GPC). Based on the results, chemical formula for the Zn(II) cysteine complex is proposed as [ZnI2(C3H5NO2S)]n. Scanning electron microscopy (SEM) analysis has demonstrated nano particles Zn(II) complex with average diameter of about 38-54 nm. Hexagonal ZnO micro structures were characterized by FTIR, X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDAX) techniques.
References (31)
- 1 Single-nanowire electrically driven lasers [DOI]
- 2 Application of Zinc Oxide Varistors [DOI]
- 3 Using sonochemistry for the fabrication of nanomaterials [DOI]
- 4 Splendid One-Dimensional Nanostructures of Zinc Oxide: A New Nanomaterial Family for Nanotechnology [DOI]
- 5 Facile Ultrasonic Synthesis of CoO Quantum Dot/Graphene Nanosheet Composites with High Lithium Storage Capacity [DOI]
- 6 Nanostructured Materials Generated by High-Intensity Ultrasound: Sonochemical Synthesis and Catalytic Studies [DOI]
- 7 Functional analysis of the cysteine synthase protein complex from plants: Structural, biochemical and regulatory properties [DOI]
- 8 Syntheses and characterization of Mg(OH)2 and MgO nanostructures by ultrasonic method [DOI]
- 9 Growth mechanism and optical property of ZnO nanoparticles synthesized by sonochemical method [DOI]
- 10 Synthesis and characterization of ZnO nanocrystals from thermolysis of new precursor [DOI]
- 11 Controllable morphology evolution of electrodeposited ZnO nano/micro-scale structures in aqueous solution [DOI]
- 12 Syntheses of BaCO3 nanostructures by ultrasonic method [DOI]
- 13 Nano-structures of two new lead(II) coordination polymers: New precursors for preparation of PbS nano-structures [DOI]
- 14 Mercury(II) Cysteine Complexes in Alkaline Aqueous Solution [DOI]
- 15 Mercury(ii) coordination polymers generated from 1,4-bis(2 or 3 or 4-pyridyl)-2,3-diaza-1,3-butadiene ligands [DOI]
- 16 Production of cysteine for bacterial and plant biotechnology: Application of cysteine feedback-insensitive isoforms of serine acetyltransferase [DOI]
- 17 A Trispyrazolylborato Iron Cysteinato Complex as a Functional Model for the Cysteine Dioxygenase [DOI]
- 18 Sonochemical syntheses of a nanoparticles cadmium(II) supramolecule as a precursor for the synthesis of cadmium(II) oxide nanoparticles [DOI]
- 19 Sonochemical synthesis of a novel nano-rod two-dimensional zinc(II) coordination polymer; preparation of zinc(II) oxide nanoparticles by direct thermolyses [DOI]
- 20 Synthesis and characterization of mercury oxide unusual nanostructures by ultrasonic method [DOI]
- 21 Sonochemical synthesis of nanocrystalline mercury sulfide, selenide and telluride in aqueous solutions [DOI]
- 22 Determination of glutathione in human plasma using high-performance liquid chromatography with electrochemical detection with a carbon-epoxy resin composite electrode chemically modified with cobalt phthalocyanine [DOI]
- 23 Syntheses of PbO nano-powders using new nano-structured lead(II) coordination polymers [DOI]
- 24 Reversible crystal to crystal transformation of a hydrogen-bonded polymer to another in a solid-gas reaction along with morphology change: nano-particles to nano-rods conversion [DOI]
- 25 Nanoparticles of a new zinc(II) coordination polymer: synthesis, characterization, thermal, and structural studies [DOI]
- 26 Detection of coronary artery disease with myocardial contrast echocardiography: comparison with 99mTc-sestamibi single-photon emission computed tomography.
- 27 Transition metal complexes of L-cysteine containing Di- and tripeptides [DOI]
- 28 Synthesis and characterization of Mn3O4 nanoparticles via thermal decomposition of a new synthesized hydrogen bonded polymer [DOI]
- 29 Structural chemistry of amino acid complexes [DOI]
- 30 Synthesis of Lead(II) Minoxidil Coordination Polymer: A New Precursor for Lead(II) Oxide and Lead(II) Hydroxyl Bromide [DOI]
- 31 Synthesis, spectroscopic and voltammetric studies of a novel Schiff-base of cysteine and saccharin [DOI]
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