Study on the Tunable LCST Properties of Phenylalaninate Derivative with Branching Oligoethyleneoxy Chains
Pan Yu, Kundan Hao, Zhou Yang, Liangchun Li
Chemical Science International Journal · pp. 1–7 · Published 7 Sep 2016
10.9734/ACSJ/2016/28842Abstract
Thermosensitive amino acid derivative with oligoethyleneoxy chains with tunable lower critical solution temperature (LCST) were prepared from L-methyl phenylalaninate and 3,5-diaminobenzoic acid derivative with oligoethyleneoxy chains. The solution properties and the effects of salt ion species on LCST of phenylalaninate derivative 11 were investigated by UV-vis. The results indicate that the LCST value of 11 could be controlled by adjusting the salt concentration with different cationic species.
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