Rhodium (I) Complexes of Quinoline Functionalised Heterocyclic Carbene Ligands
Aminu Ahmed, Abdullahi Mustapha
Chemical Science International Journal · pp. 664–675 · Published 26 Apr 2014
10.9734/ACSJ/2014/9411Abstract
In this paper, two types of quinoline functionalized rhodium complexes were synthesized by stirring imidazolium salts with silver oxide to obtain silver carbenes. According to the method, the corresponding non chelated rhodium complexes were access by transmetallation of silver carbenes. Reaction of the non chelated rhodium complexes gave the chelated analogue that was insoluble in most solvents. All the non chelated complexes were structurally characterized by 1H NMR, 13 NMR, microanalysis and X-ray crystallography. The crystal geometry of the complexes adopted square planar structures. All the rhodium complexes were stable enough in air and with moisture.
References (9)
- 1 A stable crystalline carbene [DOI]
- 2 Direct Synthesis of a Mercury Salt‐Carbene Complex [DOI]
- 3 Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation: Structure and Dynamics [DOI]
- 4 Donor‐Functionalised N‐Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions [DOI]
- 5 Oxidative Addition of the Imidazolium Cation to Zerovalent Ni, Pd, and Pt: A Combined Density Functional and Experimental Study [DOI]
- 6 Coordination Versatility of Pyridine-Functionalized N-Heterocyclic Carbenes: A Detailed Study of the Different Activation Procedures. Characterization of New Rh and Ir Compounds and Study of Their Catalytic Activity [DOI]
- 7 1Pyridine and phosphine functionalised N-heterocyclic carbene complexes of rhodium and iridium [DOI]
- 8 The coordination chemistry of bivalent group IV donors; [DOI]
- 9 Quinoline-functionalized N-heterocyclic carbene complexes of iridium: Synthesis, structures and catalytic activities in transfer hydrogenation [DOI]
Cited by 2
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