One Pot Synthesis of Cu(II) and Ni(II) Peroxo Complexes Containing Schiff Base: Physicochemical, Spectral and Antibacterial Investigations
Md. Mahasin Ali, Md. Nur Amin Bitu, Md. Saddam Hossain, Md. Faruk Hossen, Md. Ali Asraf, Md. Akhter Farooque, Md. Kudrat-E- Zahan
Asian Journal of Chemical Sciences · pp. 15–21 · Published 23 Jun 2020
10.9734/ajocs/2020/v8i119032Abstract
Two new peroxo complexes of Cu(II) and Ni(II) ion containing Schiff base (SB) were synthesized and characterized by TLC, Elemental analyses, conductivity, magnetic moment measurements, UV-Vis. and IR and ESI-MS spectral studies. The Schiff base ligand derived from cinnamaldehyde and o-aminophenol participated in complexation through a single pot reaction. IR spectra showed that the Schiff base ligand coordinated to the metal ion through nitrogen of azomethine group and oxygen of hydroxyl group & peroxo group (O-O). Magnetic moment value coupled with electronic spectral data suggested a square planar geometry for both the complexes. The molar conductance values indicated the non-electrolytic nature of the complexes. Antibacterial activity of the complexes was tested against four pathogenic bacteria, two Gram-positive Staphylococcus aureus & Bacillus cereus and two Gram-negative Escherichia coli & Shigella dysenteriae with Kanamycin (K-30) standard. The result shows that Cu(II) complex exhibited more potential antibacterial activity than the Ni(II) complex against all the tested organisms.
References (9)
- 1 Synthesis, Characterization, and Biological Activity of the Schiff Base and Its Ni(II), Cu(II), and Zn(II) Complexes Derived from 4-(Dimethylamino)benzaldehyde and S-Benzyldithiocarbazate [DOI]
- 2 New developments in the chemistry of peroxo-metal and chromium(VI)-oxidant systems [DOI]
- 3 Synthesis, characterization and catalytic behaviour of thorium peroxo complexes [DOI]
- 4 Reaction aspects of peroxo copper complexes relevant to copper containing monooxygenases. [DOI]
- 5 Metal ion activation of dioxygen
- 6 Peroxo complexes of zirconium(IV), thorium(IV), molybdenum(VI), tungsten(VI) and uranium(VI) containing two quadridentate onno Schiff bases [DOI]
- 7 Synthesis, characterization and antimicrobial activity of Co(II), Cu(II), and Mn(II) metal complexes of Schiff base ligand derived from cinnamaldehyde and ethylenediamine
- 8 Vanadium(V) and molybdenum(VI) peroxo complexes with adenine and adenosine, and the choice of donor atoms in peroxo heteroligand spheres [DOI]
- 9 Tetraalkylammonium pentacyanocobaltates. Their preparation, properties, and reactivity [DOI]
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Md. Mahasin Ali, Md. Nur Amin Bitu, Md. Saddam Hossain, Md. Faruk Hossen, Md. Ali Asraf, Md. Akter Farooque, Md. Monowar Hossain, Md. Kudrat-E- Zahan · Asian Journal of Chemical Sciences · 2020
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Showing 5 of 10 known citations — external sources report more than can currently be individually listed.
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