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Research Article Open access CC BY 4.0

Enriched Superphosphate and Ammophosphate Fertilizer Based on Washed Dried Phosphorite Concentrate

A. A. Rasulov, B. E. Sultonov

Chemical Science International Journal · pp. 55–61 · Published 14 Oct 2022

10.9734/CSJI/2022/v31i3812

Abstract

Development of a technology for obtaining enriched superphosphate and ammophosphate by processing washed and dried phosphorite concentrate (WDPC) in a single cycle. The optimal ratio P2O5WPPA:H2SO4mh :P2O5WDPC = 1:0.28:0.08 was found, at which the composition and properties of ammophosphate fertilizer are maximally improved and a single phosphorus fertilizer is additionally obtained. It has been established that on the basis of the solid part of the ammophosphate pulp, samples of enriched superphosphate are obtained with the following indicators (wt., %): Р2О5t. - 30.16-32.01; Р2О5ас.с.a. : Р2О5t. = 98.54-100; Р2О5water solubility (w.s.) : Р2О5t. = 54.3-55.5; N - 5.45-6.04. A sample of ammophosphate contains (wt., %): Р2О5t. - 52.43-53.31; Р2О5ас.с.a. : Р2О5t. = 94.81-96.27; Р2О5w.s. : Р2О5t. = 87.41-88.36; CaOt. - 4.01-4.26; N - 13.65-14.03 and SO3t. - 4.37-10.74. Ammophosphate consists of mono- and diammonium phosphate, ammonium sulfate and dicalcium phosphate. Superphosphate also contains activated phosphorite, complex salts and gypsum. The material balance of the process of their production in a single technological cycle has been calculated.

Sulfuric and phosphoric acid washed dried concentrate decomposition ammonization separation enriched superphosphate and ammophosphate chemical and salt compositions and material balance

Cited by 1

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