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Research Article Open access CC BY 4.0

Phase Relations in the Tl9TbTe6-Tl9BiTe6 System and Some Properties of Solid Solutions

S. Z. Imamaliyeva, T. M. Gasanly, M. B. Babanly

Chemical Science International Journal · pp. 1–6 · Published 6 Nov 2015

10.9734/ACSJ/2016/22221

Abstract

By using X-ray powder diffraction and differential thermal analyses, scanning electron microscopy technique and microhardness measurements the phase equilibria in the Tl9TbTe6-Tl9BiTe6 system were investigated. According to the obtained experimental results the T-x diagram and concentration dependence of the cell parameters and microhardness of alloys of the Tl9TbTe6-Tl9BiTe6 system were constructed. It is shown that the system is not quasi-binary due to the peritectic melting of Tl9TbTe6, but stable below the solidus. In the system, it is found to be continuous solid solutions with Tl5Te3 structure. These phases may be of interest to thermoelectric and magnetic materials.

Thallium-terbium telluride thallium-bismuth telluride phase equilibria solid solutions crystal structure

Cited by 2

Phase relations in the Tl5Te3-Tl9SbTe6-Tl9TbTe6 system

Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Azerbaijan National Academy of Sciences, 131 H.Javid Ave., Az-1143, Baku, Azerbaijan, Samira Imamaliyeva, Turan Gasanly · Chemistry & Chemical Technology · 2017

Phase equilibria in the Tl2Te–Tl5Te3–Tl9TbTe6 system

S. Z. Imamalieva, T. M. Gasanly, V. P. Zlomanov · Inorganic Materials · 2017

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