Synthesis and a Preliminary Characterization of Poly(Propylene)Imine Hexadecylamine Dendrimer (DAB-Am-16) Modified with  Methyl Acrylate

Devaney Ribeiro do Carmo; Tayla Fernanda Serantoni da Silveira; Rosângela Silva de Laurentiz; Urquisa Oliveira Bicalho; Leandro Martins; Newton Luiz Dias Filho; Leonardo Lataro Paim

doi:10.9734/ACSJ/2013/3818

Research Article Open access CC BY 3.0

Synthesis and a Preliminary Characterization of Poly(Propylene)Imine Hexadecylamine Dendrimer (DAB-Am-16) Modified with Methyl Acrylate

Devaney Ribeiro do Carmo, Tayla Fernanda Serantoni da Silveira, Rosângela Silva de Laurentiz, Urquisa Oliveira Bicalho, Leandro Martins, Newton Luiz Dias Filho, Leonardo Lataro Paim

Chemical Science International Journal · pp. 314–324 · Published 15 Jun 2013

10.9734/ACSJ/2013/3818

Abstract

This paper describes the reaction of a Poly(propylene)imine hexadecylamine dendrimer (DAB-Am-16) with methyl acrylate. The modified dendrimer obtained (DKMA) was characterized by vibrational spectroscopy, nuclear resonance magnetic (13C), thermogravimetry and scanning electron microscopy. The dielectric properties of DKMA were studied in a temperature range of -40 to 100°C varying the frequency from 10 to 1000 KHz. A relative thermal stability was found for DKMA. The modified dendrimer behaved as an organic insulating (ε' = 5.1). The synthesis performed at basic medium results in a corresponding change in the conformational property of the precursor. The electron microscopy indicated that the dendrimer presented a modified collapsed shape, expected by the proposed route of synthesis.

Dendrimer methyl acrylate thermal analysis dielectric properties synthesis

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Devaney Ribeiro do Carmo, Tayla Fernanda Serantoni da Silveira, Rosângela Silva de Laurentiz, Urquisa Oliveira Bicalho, Leandro Martins, Newton Luiz Dias Filho, Leonardo Lataro Paim (2013). Synthesis and a Preliminary Characterization of Poly(Propylene)Imine Hexadecylamine Dendrimer (DAB-Am-16) Modified with Methyl Acrylate. Chemical Science International Journal , 314–324. https://doi.org/10.9734/ACSJ/2013/3818

Affiliations

Devaney Ribeiro do Carmo — Department of Physics and Chemistry, Faculty of Engineering of Ilha Solteira, UNESP - Univ Estadual Paulista,, Av. Brazil Center, 56 ZIP 15385-000, Ilha Solteira, SP, Brazil
Tayla Fernanda Serantoni da Silveira — Department of Physics and Chemistry, Faculty of Engineering of Ilha Solteira, UNESP - Univ Estadual Paulista,, Av. Brazil Center, 56 ZIP 15385-000, Ilha Solteira, SP, Brazil
Rosângela Silva de Laurentiz — Department of Physics and Chemistry, Faculty of Engineering of Ilha Solteira, UNESP - Univ Estadual Paulista,, Av. Brazil Center, 56 ZIP 15385-000, Ilha Solteira, SP, Brazil
Urquisa Oliveira Bicalho — Department of Physics and Chemistry, Faculty of Engineering of Ilha Solteira, UNESP - Univ Estadual Paulista,, Av. Brazil Center, 56 ZIP 15385-000, Ilha Solteira, SP, Brazil
Leandro Martins — Institute of Chemistry of Araraquara, UNESP - Univ Estadual Paulista, Rua Francisco Degni, 55, ZIP 14801-970, Araraquara, SP, Brazil
Newton Luiz Dias Filho — Department of Physics and Chemistry, Faculty of Engineering of Ilha Solteira, UNESP - Univ Estadual Paulista,, Av. Brazil Center, 56 ZIP 15385-000, Ilha Solteira, SP, Brazil
Leonardo Lataro Paim — Institute of Chemistry of Araraquara, UNESP - Univ Estadual Paulista, Rua Francisco Degni, 55, ZIP 14801-970, Araraquara, SP, Brazil

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