Ligand (biochemistry)

Synthesis of an Electrodeficient Dipyridylbenzene-like Terdentate Ligand: Cyclometallating Ligand for Highly Emitting Iridium(III) and Platinum(II) Complexes

Pierre-Henri Lanoë, Christian Philouze & Frédérique Loiseau · Organics · 2023

Cyclometallated iridium(III) and platinum(II) complexes are intensely used in optoelectronics for their photophysical properties and ability to convert excitons from singlet to triplet state, thus improving the device efficiency. In this contribution, we report the multi-steps sy...

Open access Research Article 10.3390/org4030029

Palladium Catalyzed Allylic C-H Oxidation Enabled by Bicyclic Sulfoxide Ligands

Yuming Wen, Jianfeng Zheng, Alex H. Evans & Qiang Zhang · Organics · 2023

The activation of C-H bonds is a potent tool for modifying molecular structures in chemistry. This article details the steps involved in a novel ligand bearing a bicyclic [3.3.1]-nonane framework and bissulfoxide moiety. A palladium catalyzed allylic C-H oxidation method enables...

Open access Research Article 10.3390/org4020023