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Synthesis and Intrinsic Viscosity-molecular Weight Relationship of Poly(ethylene adipate)

Liwei Chen, Weilan Xue & Zuoxiang Zeng · Chemical Science International Journal · 2017

In this work, two series of poly (ethylene adipate) (PEA) samples with broad and narrow molecular weight distribution (MWD) were prepared by the polymerization between adipic acid and ethylene glycol. An accurate and swift method, one-point method, was used to determine the intri...

Open access Research Article 10.9734/CSJI/2017/35258

(±)-CSA Catalyzed Multicomponent Synthesis of Indeno Naphthopyrans and Tetrahydrobenzo[a]xanthen-11-ones Under Ultrasonic Irradiation

Emel Pelit · Chemical Science International Journal · 2017

Aims: This study was designed to synthesis of Naphthopyrans and xanthenes derivatives in green chemistry approach. Methodology: New 13-aryl-indeno[1,2-b]naphtha[1,2-e]pyran-12(13H)-ones and tetrahydrobenzo[a]xanthen-11-ones were obtained by multi-component reaction of 2-naphthol,...

Open access Research Article 10.9734/CSJI/2017/35380

Heavy Metals Presence in Some Vegetables and Crops Harvested From Farms in Ebocha, Egbeda and Igbo-Etche in Rivers State, Nigeria

I. A. Kalagbor, O. G. Echem, M. L. Omeokwe, H. C. Omelebele, F. Omereji & C. Onwugbuta · Chemical Science International Journal · 2017

Studies of the presence of heavy metals were carried out on some vegetables and crops harvested from farms in Ebocha, Egbeda and Igbo-Etche in Rivers State, Nigeria. These farms are located in communities where oil exploration activities are ongoing. The samples were prepared by...

Open access Research Article 10.9734/CSJI/2017/33724

Binary Complexes of Aspartic Acid with Some Metal Ions in Aqueous Solution and Water-dioxane Mixtures

Ebrahim Ghiamati, Maliheh Baniasadi & Alireza Farrokhi · Chemical Science International Journal · 2017

The reaction between amino acids and metal ions has been used as a model for transferring the metallic ions to body tissues. How stable these complexes are formed is our concern. The stability constants of the complexes between L-aspartic acid (Asp) and Co(II), Ni(II), Cu(II), Zn...

Open access Research Article 10.9734/CSJI/2017/34611

Synthesis and Characterization of Cellular Polyurethane as Redox Catalyst

Misbah Sultan, Yashfa Nazar, Aumera Khursheed, Muhammad Imran & Yusra Safa · Chemical Science International Journal · 2017

Dyes are coloring materials used extensively in common consumer products. A large amount of dye effluent is produced mainly by textile industry. These dye effluents need remediation as they are damaging water bodies and biological organisms including human beings. Polyurethane is...

Open access Research Article 10.9734/CSJI/2017/34270

Comparative Analysis of Some Digestion Methods Used in the Determination of Metals in Soil and Sediments

Innocent Joseph, H. M. Maina, Pigweh Amos Isah & J. E. Eneche · Chemical Science International Journal · 2017

Analytical study was carried in order to compare the accuracy of three (3) frequently used digestion methods, in the determination of metals in soil and sediments. Samples of soil and sediments were taken from three different locations namely; Bakalchi, Batare, and Anguwan Honna...

Open access Research Article 10.9734/CSJI/2017/34652

N,N’-Dialkylimidazolium Dimethyl Phosphates – Promising Media and Catalysts at the Same Time for Condensation Reactions

S. Brica, L. Freimane, L. Kulikovska & A. Zicmanis · Chemical Science International Journal · 2017

The objective of the current work is the elaboration of an alternative method for synthesis of N,N’-dialkylimidazolium dimethyl phosphates – ionic liquids useful both as media and catalysts for condensation reactions in organic synthesis. The proposed method consists of alkylatio...

Open access Research Article 10.9734/CSJI/2017/34482

Effective Microporosity for Enhanced Adsorption Capacity of Cr (VI) from Dilute Aqueous Solution: Isotherm and Kinetics

Lloyd Mukosha, Maurice S. Onyango, Aoyi Ochieng & John Siame · Chemical Science International Journal · 2017

The adsorbent pore structure significant to enhanced adsorption capacity of Cr (VI) from dilute aqueous solution is evaluated. As reference, low-cost micro-mesoporous activated carbon (AC) of high basicity, mesoporosity centred about 2.4 nm, and effective microporosity centred ab...

Open access Research Article 10.9734/CSJI/2017/34082

Preparation and Biodegradation of Nanocellulose Reinforced Polyvinyl Alcohol Blend Films in Bioenvironmental Media

Nusaiba Islam, Sharmin Jahan Proma & Ashiqur Rahman · Chemical Science International Journal · 2017

Solution casting method was used to prepare nanocellulose reinforced polyvinyl alcohol (PVOH) from Oil palm empty fruit bunches. Different environmental test were used to investigate the biodegradability of the composite in soil and compost as well as in water and acidic solution...

Open access Research Article 10.9734/CSJI/2017/32570

Drying Kinetics and Modelling of Mass Transfer in Thin Layer Convective Drying of Pineapple

Ravula Sudharshan Reddy, Parabhaker Reddy Ravula, Divyasree Arepally, Surender Reddy Munagala & Sheshasayana Golla · Chemical Science International Journal · 2017

The aim of the investigation was to study the drying characteristics of pineapple at different temperatures of 55, 60, 65, 70 and 75°C with 1.5 m/s constant air velocity. In the present study, the best drying model was selected to describe the drying behaviour, and to develop the...

Open access Research Article 10.9734/CSJI/2017/32746

Biodisinfection and Coagulant Properties of Mixed Garcinia kola and Carica papaya Seeds Extract for Water Treatment

O. J. Kingsely, J. C. Nnaji & B. I. Ugwu · Chemical Science International Journal · 2017

Garcinia kola (Heckel) and Carica papaya (Linn.) seeds from ripe fruits were investigated for their disinfection and coagulation activity in water. The phytochemical analysis indicated the presence of alkaloid, saponins, flavonoid and tannins in both seeds. Physicochemical analys...

Open access Research Article 10.9734/CSJI/2017/34041

Chemical Activation of Khojakul Phosphorites by Ammonium Salts

Tashkenbay Bautdinov, Akhmed Reymov & Sayfuddin Tadjiev · Chemical Science International Journal · 2017

Aims: To investigate chemical activation of low-grade phosphorite from Karakalpakstan, Khojakul by ammonium salts in order to obtain slow-acting phosphate fertilizers. Study Design: The content of the total form N (Nt.) was determined by method Kjeldahl method. Determination of t...

Open access Research Article 10.9734/CSJI/2017/30755

Novel Linearized Kinetic Modeling of Starch Hydrolysis

Nwoko Christopher Ikpe Amadi, Nkwoada Amarachi Udoka & Ihuoma Peterclever Chidi · Chemical Science International Journal · 2017

The hydrolysis of starch into glucose by acid and enzyme techniques has recorded higher glucose recovery and optimization of processes, but lacks the fitting of the results into a kinetic linear model. The application of kinetic linearized model effect of temperature on pH and ac...

Open access Research Article 10.9734/CSJI/2017/34116

Study of the Influence of Alkyl Chain Cation Solvent Interactions on the Slope of ϕv v/s √C Curves in 1, 3-Butanediol-DMF Solvent Mixtures by Apparent Molar Volume Measurements

Indu Saxena, Archna ., Rikkam Devi, Vijay Kumar, Sadhana Gautam & Jaya Tripathi · Chemical Science International Journal · 2017

The concept of Frank’s hypothesis (that is the effect of large tetra alkyl ammonium iodides on the solvent structure, especially in the ion – ion and ion – solvent interactions) was found to be not applicable when water was replaced by one of organic solvent. That is, if study in...

Open access Research Article 10.9734/CSJI/2017/33860

Relationship between Metal Concentrations in Galena Ore and Soil Samples from Galena-rich Farmlands

A. U. Itodo, I. S. Enejiv & L. A. Egbegbedia · Chemical Science International Journal · 2017

One of the Nigerian minerals (galena ore) within galena deposit region in Torkula, Benue state, was characterized along with its vicinity farmland soils for possible relationships in their geo-physico-chemical compositions. Both classical (titrimetric & gravimetric) and instr...

Open access Research Article 10.9734/CSJI/2017/32740