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Synthesis and Crystal Structure of an Air Stable Primary Phosphine-manganese (+1) Complex; fac Tricarbonyl-tris(o-fluorophenylphosphine)-Manganese(+1)-hexafluorophosphate

A. R. H. Al-Sudani, P. G. Edwards, B. M. Kariuki

International Research Journal of Pure and Applied Chemistry · pp. 1–8 · Published 12 Apr 2016

10.9734/IRJPAC/2016/25519

Abstract

The synthesis of an air-stable manganese(+I)-primary phosphine complex from fac‑[Mn(CO)3 (CH3CN)3]PF6 and (o-FC6H4)PH2 is described. The X-ray single crystal structure of the manganese (I) complex is reported.  

[{(o-FC6H4)PH2}3Mn(CO)3]PF6 crystal structure synthesis complex X-ray

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Cited by 2

Carbonyl and Isocyanide Complexes of Manganese

David C. Lacy, Sanchita Paul, Vipulan Vigneswaran · Comprehensive Organometallic Chemistry IV · 2022

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