Matrix Isolation and Computational Studies of Benzoyl Chloride Photolysis
International Research Journal of Pure and Applied Chemistry · pp. 737–745 · Published 14 Jul 2014
10.9734/IRJPAC/2014/11796Abstract
The UV light photolysis (λ >260 nm) of benzoyl chloride was investigated using matrix isolation FT-IR spectroscopy and computational methods (MP2, B3LYP, CCSD, and SAC-CI). The photolysis products were found to bechlorobenzene and CO. An intermediate species was identified with 6-chloro-2, 4-cyclohexadien-1-ylidenemethanone (CCHM) from the MP2 calculations. Changes in the CCHM absorption bands showed a typical growth and decay profile for an intermediate species in a consecutive reaction. In addition, 6-chlorofulvene was found to be a minor product.
Cited by 1
Nobuaki Tanaka, Kohei Nakamura, Masatoshi Yutaka · Chemical Physics Letters · 2014
Related research
- Cluster Ions in Vapour over Calcium Dichloride: Theoretical Study of Geometrical Structure and Vibrational Spectra — shares topic coverage
- The Static (Hyper) Polarizabilities of Push-Pull Polyenes: A Theoretic Study — shares topic coverage
- Role of the Trp-disulfide Triads in the UV Light Induced Degradation of a Monoclonal Antibody scFv — shares topic coverage
- Matrix Isolation and Theoretical Study on the Photolysis of CH2ClCOCl — shares topic coverage
- The Effects of Conformational Changes on the Native Fluorescence of Aqueous Humic Materials — shares topic coverage
Article metrics
Real usage data collected on this platform.
0
Page views
0
PDF downloads
0
Outbound clicks
1
Citations
Views by country
Approximate, from request IP at view time — not citizenship or institution. Countries with fewer than 5 views are grouped as "Other".
No views recorded yet.
Traffic sources
Referring site, by host.
No traffic recorded yet.
Views and downloads exclude known bots/crawlers. Citations combines this platform's own DOI-resolved index with each external source's own reported total — see Cited by above for individually listed citing works. Last refreshed 0 seconds ago.