Corrosion Inhibition of Mild Steel by Using Sulpha Drugs in Phosphoric Acid Medium: A Combined Experimental and Theoretical Approach
Dakeshwar Kumar Verma, Fahmida Khan
Chemical Science International Journal · pp. 1–8 · Published 7 May 2016
10.9734/ACSJ/2016/26282Abstract
The corrosion inhibition effect of Sulfacetamide and sotalol on the mild steel has been investigated in 1M H3PO4 acid medium. The inhibiting effect was investigating using weight loss measurement and quantum chemical method. The obtained results revealed that both inhibitors inhibited the mild steel corrosion in the phosphoric acid solution. The inhibitors showed more than 90% inhibition efficiency at optimum concentration. Sulfacetamide shows inhibition efficiency of 94.22 whereas sotalol shows efficiency of 91.40 at optimum concentration. Results obtained exposed that inhibition occurs through adsorption of the drugs on mild steel surface without modifying the mechanism of corrosion process obeying the Langmuir adsorption isotherm. Density functional theory (DFT) has been used to determine the relationship between molecular configuration and their inhibition efficiencies. The order of inhibition performance obtained from experimental results is successfully verified by DFT. Scanning electron microscopy (SEM) studies of the mild steel surfaces established the presence of a protective adsorbed film.
References (20)
- 1 The use of quantum chemical methods in corrosion inhibitor studies [DOI]
- 2 Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel [DOI]
- 3 Thermodynamic study of metal corrosion and inhibitor adsorption processes in mild steel/1-methyl-4[4′(-X)-styryl pyridinium iodides/hydrochloric acid systems [DOI]
- 4 Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid solutions by the extract of Murraya koenigii leaves [DOI]
- 5 Adsorption and corrosion inhibition effect of Schiff base molecules on the mild steel surface in 1 M HCl medium: a combined experimental and theoretical approach [DOI]
- 6 Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract of Punica granatum peel and main constituents [DOI]
- 7 Streptomycin: A commercially available drug as corrosion inhibitor for mild steel in hydrochloric acid solution [DOI]
- 8 The use of Euphorbia falcata extract as eco-friendly corrosion inhibitor of carbon steel in hydrochloric acid solution [DOI]
- 9 Corrosion inhibition effect of spiropyrimidinethiones on mild steel in 15% HCl solution: insight from electrochemical and quantum studies [DOI]
- 10 Green approach to corrosion inhibition of mild steel in hydrochloric acid medium using extract of spirogyra algae [DOI]
- 11 Adsorption properties and inhibition of mild steel corrosion in hydrochloric acid solution by ceftobiprole [DOI]
- 12 Corrosion inhibition of mild steel in hydrochloric acid using extract of glycine max leaves [DOI]
- 13 Eco friendly corrosion inhibitors: Inhibitive action of quinine for corrosion of low carbon steel in 1 m HCl [DOI]
- 14 Artemisia pallens as corrosion inhibitor for mild steel in HCl medium [DOI]
- 15 Ceftriaxone: a novel corrosion inhibitor for mild steel in hydrochloric acid [DOI]
- 16 Adsorption and corrosion inhibiting effect of riboflavin on Q235 mild steel corrosion in acidic environments [DOI]
- 17 The corrosion inhibition effect of aryl pyrazolo pyridines on copper in hydrochloric acid system: computational and electrochemical studies [DOI]
- 18 The inhibition effects of benzoic acid and salicylic acid on the corrosion of steel in sulfuric acid medium [DOI]
- 19 Corrosion Inhibition of High Carbon Steel in Phosphoric Acid Solution by Extract of Black Tea [DOI]
- 20 Erratum to: Investigation of the inhibition effect of ibuprofen triazole against mild steel corrosion in an acidic environment [DOI]
Cited by 4
Amit Kumar Dewangan, Yeestdev Dewangan, Dakeshwar Kumar Verma · Environmentally Sustainable Corrosion Inhibitors · 2022
Yeestdev Dewangan, Amit Kumar Dewangan, Fahmida Khan · Environmentally Sustainable Corrosion Inhibitors · 2022
Humira Assad, Ashish Kumar · Journal of Molecular Liquids · 2021
Dakeshwar Kumar Verma, Yeestdev Dewangan, Amit Kumar Dewangan · Journal of Bio- and Tribo-Corrosion · 2020
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