Adsorption and Inhibitive Effects of 2-Thiobenzylbenzimidazole (TBBI) at Aluminium Alloy AA3003/ 1M Hydrochloric Acid Interface
P. M. Niamien, A. A. Koffi, A. Trokourey
International Research Journal of Pure and Applied Chemistry · pp. 286–304 · Published 6 Dec 2012
10.9734/IRJPAC/2012/1947Abstract
The interfacial behavior of 2-Thiobenzylbenzimidazole (TBBI) between aluminium alloy AA 3003 and 1M hydrochloric acid solution was investigated by mass loss technique. Mass loss is concentration and temperature dependent. The influence of temperature has been studied in the absence and in presence of TBBI in the hydrochloric solution in the range 35-55ºC. Adsorption isotherms models including Langmuir, Temkin, Freundlich and El-Awady were tested. It was found that the inhibitor adsorbs on the metal according to the modified Langmuir adsorption isotherm. Some thermodynamic adsorption parameters ( , ) as well as activation parameters including apparent activation energy (Ea), change in activation enthalpy ( ) and change in activation entropy ( ) have been calculated and analyzed. Furthermore the Dubinin-Raduskevitch model has been used to distinguish between chemisorption and physisorption. The properties most relevant to the potential action as a corrosion inhibitor of TBBI have been calculated: highest occupied molecular orbital energy (EHOMO), lowest unoccupied molecular orbital energy (ELUMO), energy gap (ΔE), dipole moment (µ) and charges on the adsorption centers (S, N) and C atoms in benzimidazole and benzyl rings. These calculations were performed using the Gaussian suite of programs level by DFT/B3LYP/6-31G (d,p). The theoretical results are consistent with the experimental data.
References (43)
- 1 AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives [DOI]
- 2 Inhibition of aluminum corrosion using Opuntia extract [DOI]
- 3 Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid media [DOI]
- 4 Adsorption and inhibitive properties of benzimidazole derivatives in acid mild steel corrosion [DOI]
- 5 Electrochemical and theoretical investigation on the corrosion of aluminium in acidic solution containing some Schiff bases [DOI]
- 6 Antibacterial drugs as corrosion inhibitors for corrosion of aluminium in hydrochloric solution [DOI]
- 7 The effect of neutral red on the corrosion inhibition of cold rolled steel in 1.0 M hydrochloric acid [DOI]
- 8 Inhibition of acidic corrosion of pure aluminum by some organic compounds [DOI]
- 9 Effect of sodium dodecylsulfate on copper corrosion in sulfuric acid media in the absence and presence of benzotriazole [DOI]
- 10 Berberine as a natural source inhibitor for mild steel in 1M H2SO4 [DOI]
- 11 The inhibition of mild steel corrosion in acidic solutions by 2,5-bis(4-pyridyl)-1,3,4-thiadiazole: Structure–activity correlation [DOI]
- 12 Quinolin-5-ylmethylene-3-{[8-(trifluoromethyl)quinolin-4-yl]thio}propanohydrazide as an effective inhibitor of mild steel corrosion in HCl solution [DOI]
- 13 Evaluation of the inhibitory effect of methylene blue dye on the corrosion of aluminium in hydrochloric acid [DOI]
- 14 Corrosion inhibition of mild steel in acidic medium by some sulfa drugs compounds [DOI]
- 15 Inhibition effect of nonionic surfactant on the corrosion of cold rolled steel in hydrochloric acid [DOI]
- 16 The synergistic effect of polyacrylamide and iodide ions on the corrosion inhibition of mild steel in H2SO4 [DOI]
- 17 The effect of temperature on the corrosion of mild steel in acidic media in the presence of some sulphur-containing organic compounds [DOI]
- 18 2-Mercapto-1-methylimidazole as corrosion inhibitor for copper in hydrochloric acid [DOI]
- 19 Inhibition of acid corrosion of aluminum using vanillin [DOI]
- 20 Potential of aqueous extract of Hibiscus sabdariffa leaves for inhibiting the corrosion of aluminum in alkaline solutions [DOI]
- 21 Crevice corrosion of stainless steels in sodium chloride solution [DOI]
- 22 The role of some thiosemicarbazide derivatives in the corrosion inhibition of aluminium in hydrochloric acid [DOI]
- 23 Piperidine, piperidones and tetrahydrothiopyrones as inhibitors for the corrosion of copper in H2SO4 [DOI]
- 24 The effect of molecular structure on hydrogen permeation and the corrosion inhibition of mild steel in acidic solutions [DOI]
- 25 AC-Impedance measurements on aluminium in chloride containing solutions and below the pitting potential [DOI]
- 26 Electrochemical study of the pitting corrosion of aluminium and its alloys—II. Study of the interaction of chloride ions with a passive film on aluminium and initiation of pitting corrosion [DOI]
- 27 Corrosion Inhibition of a Mild Steel by Aniline and Alkylamines in Acidic Solutions [DOI]
- 28 Interfacial behavior of 4-(2-pyridylazo) resorcin between steel and hydrochloric acid [DOI]
- 29 INHIBITORY EFFECT AND ADSORPTION CHARACTERISTICS OF 2,3-DIAMINONAPHTHALENE AT ALUMINUM/HYDROCHLORIC ACID INTERFACE: EXPERIMENTAL AND THEORETICAL STUDY [DOI]
- 30 Nicotinic acid as a nontoxic corrosion inhibitor for hot dipped Zn and Zn–Al alloy coatings on steels in diluted hydrochloric acid [DOI]
- 31 Study of the Inhibitory Action of Nitrogen-Containing Compounds [DOI]
- 32 Technical noteInfluence of molecular structure of substituted benzothiazoles on corrosion inhibition and hydrogen permeation through mild steel in sulphuric acid [DOI]
- 33 Adsorption and corrosive inhibitive properties ofVigna unguiculatain alkaline and acidic media [DOI]
- 34 Activation of aluminium in chloride containing solutions [DOI]
- 35 Comparative study of the effect of inorganic ions on the corrosion of Al 3003 and 6063 in carbonate solution [DOI]
- 36 The Effect of pH of Zero Charge on the Pitting Potential [DOI]
- 37 Electrochemical study of the pitting corrosion of aluminium and its alloys—I. Determination of critical pitting and protection potentials [DOI]
- 38 Organic Corrosion Inhibitors for Aluminum in Perchloric Acid [DOI]
- 39 Inhibition of corrosion of aluminium-51S in hydrochloric acid solutions [DOI]
- 40 Inhibition of the acid corrosion of aluminium by some derivatives of thiosemicarbazone [DOI]
- 41 Technical Note: Role of Imidazolone Derivatives in Corrosion Inhibition of Pure Aluminum in Hydrochloric Acid Solution [DOI]
- 42 Corrosion inhibition of aluminum alloys in heat exchanger systems [DOI]
- 43 The effect of some hydrazine derivatives on the corrosion of Al in HCl solution [DOI]
Cited by 9
F.O. Edoziuno, A.A. Adediran, B.U. Odoni · Results in Engineering · 2021
F. O. Edoziuno, A. A. Adediran, B. U. Odoni · The Scientific World Journal · 2020
Hiba Messaoudi, Fayçal Djazi, Mohamed Litim · Journal of Adhesion Science and Technology · 2020
M.A. Deyab, Q. Mohsen, Omnia A.A. El-Shamy · Colloids and Surfaces A: Physicochemical and Engineering Aspects · 2024
Showing 4 of 9 known citations — external sources report more than can currently be individually listed.
Related research
- Adsorption Isotherms of Extruded Bambara Groundnut (Vigna subterranea) Based Ready-to-eat Breakfast Meal — shares topic coverage
- Azo Dye Removal from Aqueous Solutions Using Laccase-modified Red Mud: Adsorption Kinetics and Isotherm Studies — shares topic coverage
- Adsorption Isotherm and Thermodynamic Profile of Hexavalent Chromium onto Lumbang (Aleurites moluccana) Activated Carbon Chitosan Composite Crosslinked with Epichlorohydrin — shares topic coverage
- Experimental Analysis of Shale for Evaluating Shale Drilling Fluid Interaction in Agbada Formation — shares topic coverage
- Kinetic, Equilibrium and Thermodynamic Studies of the Adsorption of Methylene Blue from Synthetic Wastewater Using Cow Hooves — shares topic coverage
Article metrics
Real usage data collected on this platform.
72
Page views
0
PDF downloads
30
Outbound clicks
9
Citations
Views over time
Views by country
Approximate, from request IP at view time — not citizenship or institution. Countries with fewer than 5 views are grouped as "Other".
Traffic sources
Referring site, by host.
Views and downloads exclude known bots/crawlers. Citations combines this platform's own DOI-resolved index with each external source's own reported total — see Cited by above for individually listed citing works. Last refreshed 0 seconds ago.