Carla M. Ormachea

Diels–Alder Polar Reactions of Azaheterocycles: A Theoretical and Experimental Study

Carla M. Ormachea, María Nélida Kneeteman & Pedro M. E. Mancini · Organics · 2022

A number of azaheterocycles (pyridines, pyrroles and indoles) have been properly functionalized so that they can act as dienophiles in cycloaddition Diels–Alder processes. This work analyzed the reactive behavior of these molecules through mechanistic analysis and the regioselect...

Open access Research Article 10.3390/org3020008

A Theoretical Study of 2-nitrofuran vs 3-nitrofuran as Dienophilic Electrophile in Polar Cycloaddition Reaction: Comparison of the Reactivity and Reaction Mechanism

Mauro Cainelli, Carla M. Ormachea, Pedro M. E. Mancini & María N. Kneeteman · International Research Journal of Pure and Applied Chemistry · 2016

In this study, we analyzed in a theoretical form the behavior of 2-nitrofuran and 3-nitrofuran acting as dienophilic electrophiles in polar cycloaddition reactions joint to different dienes. The reactivity and regioselectivity was discussed employing global and local reactivity i...

Open access Research Article 10.9734/IRJPAC/2016/30222

A Theoretical Study of the Diels-Alder Reaction between 3-nitrofuran and Different Dienes Developed in Ionic Liquids

Mauro Cainelli, Carla M. Ormachea, María N. Kneeteman & Pedro M. E. Mancini · International Research Journal of Pure and Applied Chemistry · 2016

In this study the reactivity of 3-nitrofuran acting as electrophile in their reactions with different dienes, was analyzed in theoretical form. Specifically, the mechanism of each DA reaction was explored. Moreover, considering the polar character of this type of cycloaddition re...

Open access Research Article 10.9734/IRJPAC/2016/27380